QuestAir to supply biogas purification systems to Swiss company
Biogas holds a large potential to replace natural gas, both in Europe (earlier post), as well as in the developing world.
The green, climate-neutral gas can be made efficiently from the anaerobic fermentation of a wide variety of organic feedstocks, either derived from dedicated bioenergy crops (earlier post on biogas maize, grasses and grass hybrids)or from waste streams from agriculture, municipalities or industry.
An interesting development in the field of large-scale biogas production is that of feeding the gas into the natural gas grid. In Europe, several companies are already doing this (earlier post). In the same context, the concept of 'biogas corridors' is gaining attention (earlier post). It consists of the simple idea of establishing energy plantations and biogas plants close to existing natural gas pipelines, which can then be supplied with the green gas.
But for the idea to work, efficient biogas purification technologies must be developed. Depending on the biomass feedstock, raw biogas has methane concentrations of around 55 to 70%, with the remainder being carbon dioxide, water, hydrogen sulfide and particulates. For it to be fed into the natural gas grid, the biomethane must be scrubbed and reach methane concentrations of more than 96%. Once the purified green gas is mixed into the grid, end consumers of course do not note the difference, biogas can be used just like its fossil counterpart: in power plants, by households, in fuel cells or as a fuel for CNG-capable vehicles.
Several biogas purification technologies currently exist, with some interesting innovations being made. One of the innovators is Canadian company QuestAir Technologies Inc., which announced that it has received an order for its compact M-3200 'Pressure Swing Adsorption' system to recover pipeline grade methane from biogas generated by an anaerobic digester in Lavigny, Switzerland.
This system, using an optimised pressure swing adsorption (PSA) process and a proprietary rotary valve technology delivers a higher efficiency than conventional PSA systems in a more compact, cost effective package. QuestAir’s M-3200 system can upgrade up to 300,000 cubic feet (8500 cubic meters) of biogas per day.
PSA is a commonly used technology for purifying gases. The technology was introduced commercially in the 1960's and today PSA is used extensively in the production and purification of oxygen, nitrogen and hydrogen for industrial uses. PSA is based on the capacity of certain materials, such as activated carbon and zeolites, to adsorb and desorb particular gases as the gas pressure is raised and lowered. PSA can be used to separate a single gas from a mixture of gases. A typical PSA system involves a cyclic process where a number of connected vessels containing adsorbent material undergo successive pressurization and depressurization steps in order to produce a continuous stream of purified product gas.
The operation of a simplified PSA process to separate methane from a feedstock gas containing impurities, such as carbon dioxide, carbon monoxide or water is illustrated in the diagram (see diagram, click to enlarge).
Conventional PSA systems used today in industry are made up of four to 16 large vessels, connected by a complex network of piping and valves to switch the gas flows between the vessels. Despite their widespread use in industry, QuestAir believes that large scale PSA systems suffer from a number of inherent disadvantages. These PSA systems typically operate at slow cycle speeds of 0.05-0.5 cycles/minute since faster cycle speeds would cause the adsorbent beads to float or "fluidize" in the vessel, causing the beads to wear and ultimately fail. To meet customer demands for capacity, conventional PSA systems must utilize large vessels to compensate for the slow cycle speeds, leading to higher costs and a large equipment footprint. The use of large vessels also means that these PSA systems are typically erected in the field, increasing installation costs. The network of piping and valves used in large scale PSA systems, with the associated instrumentation and process control equipment, also adds cost to the overall system. QuestAir's simplified PSA system is far more compact, modular and cost effective.
We focus on this technology, as it opens up very interesting opportunities for decentralised bioenergy production in the developing world, even though they are not to be realised in the immediate future:
biomass :: bioenergy :: biofuels :: energy :: sustainability :: purification ::biogas :: biomethane :: natural gas ::
Many countries in the tropics and the subtropics have a large potential both to recover biomethane from organic waste streams, especially in large cities, as for its productio based on energy crops and agro-forestry residues.
A compact biogas purification system like that of QuestAir, allows for a decentralised production scenario that results in high quality gas, capable of fuelling CNG-vehicles.
Compared to other 'first generation' liquid biofuels, biogas production is more energy efficient, it yields a greater amount of energy on a per hectare basis. With a modular, portable purification system now available, decentralised motor fuel production centres can be established in areas previously unreachable by ordinary fossil fuels (such as oil and natural gas).
Such a decentralised system would side-step the need to extend natural gas and oil pipeline grids, and instead could be established locally. CNG-capable fleets can be introduced in remote locations, and bought off the shelf without the need for modifications, as they would run on highly purified biogas.
Alternatively, a scenario of biogas exports is not unthinkable. Several liquefied natural gas (LNG) facilities are being build in the South (notably in Equatorial Guinea, Nigeria and Angola) wich, just like the existing ones (in Malaysia and Indonesia), could be supplied by purified biogas. This green gas would then be fed into the LNG plant and be shipped to world markets, where it would fetch premium prices because it is CO2 neutral and renewable.
Currently, the production costs implied under these scenarios are prohibitive, but the concept as such is feasible. With technological advances being made in the sector, which will result in steady decreases in production costs, these scenarios will become practicable. Not in the least given a future of 'peak oil and gas' and price-tags being put on carbon dioxide.
It will be interesting to follow up on the Swiss case first, and see how it develops. If successful, there is no reason for developing countries not to adopt similar technologies.
QuestAir's purification system has been purchased by Verdesis Suisse SA as part of a new plant that will recover methane from biogas generated by the anaerobic digestion of organic wastes at the Lavigny site. The methane recovery plant will be owned and operated Cosvegaz S.A., a Swiss gas utility, and product methane from the plant will be injected into the local natural gas distribution grid operated by Cosvegaz.
Jonathan Wilkinson, President and CEO of QuestAir said: “We are extremely pleased to secure our first sale into the European biogas market, which represents an exciting growth opportunity for QuestAir. We have seen growing interest across the EU in the use of renewable sources of methane to supplement or replace imported natural gas. In addition, government programs in several EU countries are promoting the use of biogas as a carbon neutral source of compressed natural gas (CNG) transportation fuel for busses and cars.”
“QuestAir’s methane recovery systems offer a compact solution for cost-effectively removing carbon dioxide and other impurities from biogas, recovering high purity methane for high value end-uses,” Wilkinson said.
Meanwhile, German scientists are developing bio-based biogas purification systems. They are looking into using micro-organisms and algae that feed on the CO2 contained in biomethane. Pilot trials show this concept to hold some promise (earlier post).
Article continues
The green, climate-neutral gas can be made efficiently from the anaerobic fermentation of a wide variety of organic feedstocks, either derived from dedicated bioenergy crops (earlier post on biogas maize, grasses and grass hybrids)or from waste streams from agriculture, municipalities or industry.
An interesting development in the field of large-scale biogas production is that of feeding the gas into the natural gas grid. In Europe, several companies are already doing this (earlier post). In the same context, the concept of 'biogas corridors' is gaining attention (earlier post). It consists of the simple idea of establishing energy plantations and biogas plants close to existing natural gas pipelines, which can then be supplied with the green gas.
But for the idea to work, efficient biogas purification technologies must be developed. Depending on the biomass feedstock, raw biogas has methane concentrations of around 55 to 70%, with the remainder being carbon dioxide, water, hydrogen sulfide and particulates. For it to be fed into the natural gas grid, the biomethane must be scrubbed and reach methane concentrations of more than 96%. Once the purified green gas is mixed into the grid, end consumers of course do not note the difference, biogas can be used just like its fossil counterpart: in power plants, by households, in fuel cells or as a fuel for CNG-capable vehicles.
Several biogas purification technologies currently exist, with some interesting innovations being made. One of the innovators is Canadian company QuestAir Technologies Inc., which announced that it has received an order for its compact M-3200 'Pressure Swing Adsorption' system to recover pipeline grade methane from biogas generated by an anaerobic digester in Lavigny, Switzerland.
This system, using an optimised pressure swing adsorption (PSA) process and a proprietary rotary valve technology delivers a higher efficiency than conventional PSA systems in a more compact, cost effective package. QuestAir’s M-3200 system can upgrade up to 300,000 cubic feet (8500 cubic meters) of biogas per day.
PSA is a commonly used technology for purifying gases. The technology was introduced commercially in the 1960's and today PSA is used extensively in the production and purification of oxygen, nitrogen and hydrogen for industrial uses. PSA is based on the capacity of certain materials, such as activated carbon and zeolites, to adsorb and desorb particular gases as the gas pressure is raised and lowered. PSA can be used to separate a single gas from a mixture of gases. A typical PSA system involves a cyclic process where a number of connected vessels containing adsorbent material undergo successive pressurization and depressurization steps in order to produce a continuous stream of purified product gas.
The operation of a simplified PSA process to separate methane from a feedstock gas containing impurities, such as carbon dioxide, carbon monoxide or water is illustrated in the diagram (see diagram, click to enlarge).
Conventional PSA systems used today in industry are made up of four to 16 large vessels, connected by a complex network of piping and valves to switch the gas flows between the vessels. Despite their widespread use in industry, QuestAir believes that large scale PSA systems suffer from a number of inherent disadvantages. These PSA systems typically operate at slow cycle speeds of 0.05-0.5 cycles/minute since faster cycle speeds would cause the adsorbent beads to float or "fluidize" in the vessel, causing the beads to wear and ultimately fail. To meet customer demands for capacity, conventional PSA systems must utilize large vessels to compensate for the slow cycle speeds, leading to higher costs and a large equipment footprint. The use of large vessels also means that these PSA systems are typically erected in the field, increasing installation costs. The network of piping and valves used in large scale PSA systems, with the associated instrumentation and process control equipment, also adds cost to the overall system. QuestAir's simplified PSA system is far more compact, modular and cost effective.
We focus on this technology, as it opens up very interesting opportunities for decentralised bioenergy production in the developing world, even though they are not to be realised in the immediate future:
biomass :: bioenergy :: biofuels :: energy :: sustainability :: purification ::biogas :: biomethane :: natural gas ::
Many countries in the tropics and the subtropics have a large potential both to recover biomethane from organic waste streams, especially in large cities, as for its productio based on energy crops and agro-forestry residues.
A compact biogas purification system like that of QuestAir, allows for a decentralised production scenario that results in high quality gas, capable of fuelling CNG-vehicles.
Compared to other 'first generation' liquid biofuels, biogas production is more energy efficient, it yields a greater amount of energy on a per hectare basis. With a modular, portable purification system now available, decentralised motor fuel production centres can be established in areas previously unreachable by ordinary fossil fuels (such as oil and natural gas).
Such a decentralised system would side-step the need to extend natural gas and oil pipeline grids, and instead could be established locally. CNG-capable fleets can be introduced in remote locations, and bought off the shelf without the need for modifications, as they would run on highly purified biogas.
Alternatively, a scenario of biogas exports is not unthinkable. Several liquefied natural gas (LNG) facilities are being build in the South (notably in Equatorial Guinea, Nigeria and Angola) wich, just like the existing ones (in Malaysia and Indonesia), could be supplied by purified biogas. This green gas would then be fed into the LNG plant and be shipped to world markets, where it would fetch premium prices because it is CO2 neutral and renewable.
Currently, the production costs implied under these scenarios are prohibitive, but the concept as such is feasible. With technological advances being made in the sector, which will result in steady decreases in production costs, these scenarios will become practicable. Not in the least given a future of 'peak oil and gas' and price-tags being put on carbon dioxide.
It will be interesting to follow up on the Swiss case first, and see how it develops. If successful, there is no reason for developing countries not to adopt similar technologies.
QuestAir's purification system has been purchased by Verdesis Suisse SA as part of a new plant that will recover methane from biogas generated by the anaerobic digestion of organic wastes at the Lavigny site. The methane recovery plant will be owned and operated Cosvegaz S.A., a Swiss gas utility, and product methane from the plant will be injected into the local natural gas distribution grid operated by Cosvegaz.
Jonathan Wilkinson, President and CEO of QuestAir said: “We are extremely pleased to secure our first sale into the European biogas market, which represents an exciting growth opportunity for QuestAir. We have seen growing interest across the EU in the use of renewable sources of methane to supplement or replace imported natural gas. In addition, government programs in several EU countries are promoting the use of biogas as a carbon neutral source of compressed natural gas (CNG) transportation fuel for busses and cars.”
“QuestAir’s methane recovery systems offer a compact solution for cost-effectively removing carbon dioxide and other impurities from biogas, recovering high purity methane for high value end-uses,” Wilkinson said.
Meanwhile, German scientists are developing bio-based biogas purification systems. They are looking into using micro-organisms and algae that feed on the CO2 contained in biomethane. Pilot trials show this concept to hold some promise (earlier post).
Article continues
Monday, March 12, 2007
Biomass-to-liquids in Brazil
But the North is investing heavily in so-called 'second generation' biofuels, which utilize a far wider variety of biomass feedstocks, such as wood chips and agro-forestry residues. These ligno-cellulosic feedstocks can be converted into liquid fuels via a biochemical conversion process, using special enzymes, or via a thermochemical process based on biomass gasification and Fischer-Tropsch synthesis ('biomass-to-liquids'), which results in 'synthetic' biofuels (earlier post). The North hopes these technologies will ultimately surpass the efficiency of biofuels produced in the South.
Obviously, this will not be the case if countries in the tropics and subtropics utilize the very same processes. The basic fact remains that biomass productivity in the South is naturally higher than that in temperate climates, resulting in competitive advantages that cannot be changed fundamentally. Consequently, the entire discussion about trade barriers and biofuel subsidies will not become obsolete with the arrival of second generation biofuels. (For a good and frequently updated overview of the Brazilian perspective on biofuel trade discussions, check Henrique Oliveira's Ethablog).
After decades of investments in an ultimately highly successful first generation biofuel - sugarcane ethanol - Brazil now is waking up to the potential of these next-generation biofuels. Proof is an interesting overview written for the Energy Tribune by Fernando B. de Oliveira, a process engineer, and Sirlei S. A. de Sousa, is a senior gas-to-liquids consultant at the Petrobras R&D Center in Rio de Janeiro. We replicate their 'opinion piece' here integrally, for future reference. The authors make the case as to why second-generation biofuels produced in the South will be far more competitive than those produced in the US or the EU.
The following is their analysis of the potential to generate liquid hydrocarbons through gasification and Fischer-Tropsch synthesis from two abundantly available biomass streams in Brazil, namely wood and bagasse. The wood stream would come from dedicated energy plantations in which trees like Eucalyptus and Acacia would be grown in short-rotation cycles. A recent analysis by a consortium of European academic institutions put Brazil's explicitly sustainable long-term wood plantation potential at 46 million hectares (earlier post). Bagasse, the other biomass resource, is a byproduct from first generation sugarcane ethanol production:
biomass :: bioenergy :: biofuels :: energy :: sustainability :: sugarcane :: bagasse :: eucalyptus :: energy crops :: cellulosic ethanol :: gasification :: Fischer-Tropsch :: synthetic biofuels :: Brazil ::
Biomass to Liquid process (Fischer-Tropsch synthesis)
The synthesis of hydrocarbons from carbon monoxide, CO hydrogenation over transition metal catalysts, was discovered in 1902. Collectively, the process of converting CO and H2 mixtures to liquid hydrocarbons over a transition metal catalyst has become known as the Fischer-Tropsch synthesis. Two main characteristics of FTS are the unavoidable production of a wide range of hydrocarbon products and the liberation of a large amount of heat from the highly exothermic synthesis reactions.
Consequently, reactor design and process development has focused heavily on heat removal and temperature control. The focus of catalyst development is on improved catalyst lifetimes, activity, and selectivity. Product distributions are influenced by temperature, feed gas composition (H2/CO), pressure, and catalyst type and composition. There are four main steps to producing FT products: syngas generation, gas purification, FT synthesis, and product upgrading.
When the feedstock is biomass, its conversion to a suitable feed gas for FTS, containing H2 and CO, takes place through gasification. But in this case, a pre-treatment prior to gasification is required, and generally consists of screening, size reduction, magnetic separation, “wet” storage, drying, and “dry” storage. Gasification can take place at different pressures, either directly or indirectly heated (lower temperatures), and with oxygen or air. Direct heating occurs by partial oxidation of the feedstock, while indirect heating occurs through a heat exchange mechanism. Upgrading usually means a combination of hydrotreating, hydrocracking, and hydroisomerization in addition to product separation. Unlike conventional fuels, FT fuels contain no sulfur and low aromatics. These properties, along with a high cetane number, result in superior combustion characteristics.
Discussion
From the information available in the literature, our studies suggest the use of a process, based on the FTS, aiming at the best use of wood and sugarcane byproducts (bagasse/trash) for the production of high-quality liquid byproducts, such as diesel, naphtha, base oils, and paraffin, and also the concomitant generation of electricity.
The scheme of the chosen process involves the following steps: biomass pre-treatment section, generation of syngas through the gasification process (atmospheric fluidized bed air blown gasifier), and adjustment of the ratio of the H2/CO to be fed to the Fischer-Tropsch reactor (cobalt-based catalyst) through a shift reactor. In Tables 1 and 2, the elementary and immediate analyses of biomass can be found in percentage weight adopted in this study.
Table 3 shows the results of biomass consumption for their two feedstocks, aiming at the production of high-quality liquid byproducts as well as electric power generation.
The results listed in Table 3 show a decrease of around 13 percent in the consumption of biomass when wood is used to supply the process. The advantages and disadvantages of this scheme need to be studied further, considering, for example, the availability and cost of the raw materials.
Using entirely the syngas generated in the gasification stage, this study also estimated (Table 4) the potential for electric power generation considering a Combined Cycle – CC – and a Condensing Extraction Steam Turbine – CEST.
Electricity Generation
It is important to point out that FTS produces a residual gas stream that may be used to generate electric power through a combined cycle. This allows the sugarcane bagasse to be directed towards plant BTL, thus increasing the production of liquid byproducts and keeping the electric power generation for use by the plant and/or neighborhoods. Various studies are currently trying to perfect the generation of electric power and the production of liquid byproducts with or without power generation via FTS.
All start from the most diversified generators of biomass, aiming to increase the use of this kind of raw material for the world’s energy sources, thus decreasing dependence on non-renewables. Currently, most efforts are concentrated on the development of adequate gasification processes for each type of biomass.
In the case of Brazil, some studies have already demonstrated the viability of bagasse and trash from sugarcane processing as a feedstock in ethanol fuel mills.
Article continues
posted by Biopact team at 4:59 PM 0 comments links to this post