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    Spanish energy and engineering group Abengoa will spend more than €1 billion (US$1.35 billion) over the next three years to boost its bioethanol production, Chairman Javier Salgado said on Tuesday. The firm is studying building four new plants in Europe and another four in the United States. Reuters - May 23, 2007.

    According to The Nikkei, Toyota is about to introduce flex-fuel cars in Brazil, at a time when 8 out of 10 new cars sold in the country are already flex fuel. Brazilians prefer ethanol because it is about half the price of gasoline. Forbes - May 22, 2007.

    Virgin Trains is conducting biodiesel tests with one of its diesel engines and will be running a Voyager train on a 20 percent biodiesel blend in the summer. Virgin Trains Media Room - May 22, 2007.

    Australian mining and earthmoving contractor Piacentini & Son will use biodiesel from South Perth's Australian Renewable Fuels across its entire fleet, with plans to purchase up to 8 million litres from the company in the next 12 months. Tests with B20 began in October 2006 and Piacentinis reports very positive results for economy, power and maintenance. Western Australia Business News - May 22, 2007.

    Malaysia's Plantation Industries and Commodities Minister Datuk Peter Chin Fah Kui announces he will head a delegation to the EU in June, "to counter European anti-palm oil activists on their own home ground". The South East Asian palm oil industry is seen by many European civil society organisations and policy makers as unsustainable and responsible for heavy deforestation. Malaysia Star - May 20, 2007.

    Paraguay and Brazil kick off a top-level seminar on biofuels, cooperation on which they see as 'strategic' from an energy security perspective. 'Biocombustiveis Paraguai-Brasil: Integração, Produção e Oportunidade de Negócios' is a top-level meeting bringing together the leaders of both countries as well as energy and agricultural experts. The aim is to internationalise the biofuels industry and to use it as a tool to strengthen regional integration and South-South cooperation. PanoramaBrasil [*Portuguese] - May 19, 2007.

    Portugal's Galp Energia SGPS and Petrobras SA have signed a memorandum of understanding to set up a biofuels joint venture. The joint venture will undertake technical and financial feasibility studies to set up a plant in Brazil to export biofuels to Portugal. Forbes - May 19, 2007.

    The Cypriot parliament has rejected an amendment by President Papadopoulos on the law regarding the use of biofuels that contain genetically modified substances. The amendment called for an alteration in the law that currently did not allow the import or use of biofuels that had been produced using GM substances, something that goes against a recent EU Directive on GMOs. Cyprus Mail - May 18, 2007.

    According to Salvador Rivas, the director for Non-Conventional Energy at the Dominican Republic's Industry and Commerce Ministry, a group of companies from Brazil wants to invest more than 100 million dollars to produce ethanol in the country, both for local consumption and export to the United States. Dominican Today - May 16, 2007.

    EWE AG, a German multi-service energy company, has started construction on a plant aimed at purifying biogas so that it can be fed into the natural gas grid. Before the end of the year, EWE AG will be selling the biogas to end users via its subsidiary EWE Naturwatt. Solarthemen [*German] - May 16, 2007.

    Scania will introduce an ethanol-fueled hybrid bus concept at the UITP public transport congress in Helsinki 21-24 May 2007. The full-size low-floor city bus is designed to cut fossil CO2 emissions by up to 90% when running on the ethanol blend and reduce fuel consumption by at least 25%. GreenCarCongress - May 16, 2007.

    A report by the NGO Christian Aid predicts there may be 1 billion climate refugees and migrants by 2050. It shows the effects of conflicts on populations in poor countries and draws parallels with the situation as it could develop because of climate change. Christian Aid - May 14, 2007.

    Dutch multinational oil group Rompetrol, also known as TRG, has entered the biofuel market in France in conjunction with its French subsidiary Dyneff. It hopes to equip approximately 30 filling stations to provide superethanol E85 distribution to French consumers by the end of 2007. Energy Business Review - May 13, 2007.

    A group of British organisations launches the National Forum on Bio-Methane as a Road Transport Fuel. Bio-methane or biogas is widely regarded as the cleanest of all transport fuels, even cleaner than hydrogen or electric vehicles. Several EU projects across the Union have shown its viability. The UK forum was lauched at the Naturally Gas conference on 1st May 2007 in Loughborough, which was hosted by Cenex in partnership with the NSCA and the Natural Gas Vehicle Association. NSCA - May 11, 2007.

    We reported earlier on Dynamotive and Tecna SA's initiative to build 6 bio-oil plants in the Argentinian province of Corrientes (here). Dynamotive has now officially confirmed this news. Dynamotive - May 11, 2007.

    Nigeria launches a national biofuels feasibility study that will look at the potential to link the agricultural sector to the automotive fuels sector. Tim Gbugu, project leader, said "if we are able to link agriculture, we will have large employment opportunity for the sustenance of this country, we have vast land that can be utilised". This Day Onlin (Lagos) - May 9, 2007.

    Brazilian President Luiz Inácio Lula da Silva meets with the CEO of Portuguese energy company Galp Energia, which will sign a biofuel cooperation agreement with Brazilian state-owned oil company Petrobras. GP1 (*Portuguese) - May 9, 2007.

    The BBC has an interesting story on how biodiesel made from coconut oil is taking the pacific island of Bougainville by storm. Small refineries turn the oil into an affordable fuel that replaces costly imported petroleum products. BBC - May 8, 2007.

    Indian car manufacturer Mahindra & Mahindra is set to launch its first B100-powered vehicles for commercial use by this year-end. The company is confident of fitting the new engines in all its existing models. Sify - May 8, 2007.

    The Biofuels Act of the Philippines has come into effect today. The law requires all oil firms in the country to blend 2% biodiesel (most often coconut-methyl ester) in their diesel products. AHN - May 7, 2007.

    Successful tests based on EU-criteria result in approval of 5 new maize hybrids that were developed as dedicated biogas crops [*German]. Veredlungsproduktion - May 6, 2007.

    With funding from the U.S. Department of Labor Workforce Innovation for Regional Economic Development (WIRED), Michigan State University intends to open a training facility dedicated to students and workers who want to start a career in the State's growing bioeconomy. Michigan State University - May 4, 2007.

    Researchers from the Texas A&M University have presented a "giant" sorghum variety for the production of ethanol. The crop is drought-tolerant and yields high amounts of ethanol. Texas A & M - May 3, 2007.

    C-Tran, the public transportation system serving Southwest Washington and parts of Portland, has converted its 97-bus fleet and other diesel vehicles to run on a blend of 20% biodiesel beginning 1 May from its current fleet-wide use of B5. Automotive World - May 3, 2007.

    The Institut Français du Pétrole (IFP) and France's largest research organisation, the CNRS, have signed a framework-agreement to cooperate on the development of new energy technologies, including research into biomass based fuels and products, as well as carbon capture and storage technologies. CNRS - April 30, 2007.

    One of India's largest state-owned bus companies, the Andra Pradesh State Road Transport Corporation is to use biodiesel in one depot of each of the 23 districts of the state. The company operates some 22,000 buses that use 330 million liters of diesel per year. Times of India - April 30, 2007.

    Indian sugar producers face surpluses after a bumper harvest and low prices. Diverting excess sugar into the ethanol industry now becomes more attractive. India is the world's second largest sugar producer. NDTVProfit - April 30, 2007.

    Brazilian President Luiz Inacio Lula da Silva and his Chilean counterpart Michelle Bachelet on Thursday signed a biofuel cooperation agreement designed to share Brazil's experience in ethanol production and help Chile develop biofuels and fuel which Lula seeks to promote in other countries. More info to follow. People's Daily Online - April 27, 2007.

    Italy's Benetton plans to build a €61 million wood processing and biomass pellet production factory Nagyatád (southwest Hungary). The plant will be powered by biogas. Budapest Sun - April 27, 2007.

    Cargill is to build an ethanol plant in the Magdeburger Börde, located on the river Elbe, Germany. The facility, which will be integrated into existing starch processing plant, will have an annual capacity of 100,000 cubic meters and use grain as its feedstock. FIF - April 26, 2007.

    Wärtsilä Corporation was awarded a contract by the Belgian independent power producer Renogen S.A. to supply a second biomass-fuelled combined heat and power plant in the municipality of Amel in the Ardennes, Belgium. The new plant will have a net electrical power output of 3.29 MWe, and a thermal output of up to 10 MWth for district heating. The electrical output in condensing operation is 5.3 MWe. Kauppalehti - April 25, 2007.

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Wednesday, May 23, 2007

Boost to biohydrogen: high yield production from starch by synthetic enzymes

In what is a breakthrough for the hydrogen economy, scientists from Virginia Tech, Oak Ridge National Laboratory (ORNL), and the University of Georgia announce they have developed a biohydrogen production technique that tackles most of the problems traditionally associated with the production, storage and distribution of hydrogen. Their concept implies we may soon be filling our tanks with dry starch, the powdery stuff sold in grocery stores. Synthetic enzymes will do the rest.

This development gives new hope to the hydrogen economy. As part of what can be called the larger 'carbohydrate economy' the gas will be produced efficiently from starch and sugar-rich biomass instead of expensive and dirty alternatives like coal and natural gas. The new biohydrogen production method is also more efficient and cost-competitive than making the gas from water, which is based on using expensive electricity obtained from nuclear, wind or solar to power the electrolysis process.

According to experts, for hydrogen to penetrate the market for transportation, advances are needed in four areas: production, storage, distribution, and fuel cells. Most industrial hydrogen currently comes from natural gas, which has become expensive and contributes to climate change. Storing and moving the gas, whatever its source, is costly and cumbersome, and even dangerous. And there is little infrastructure for refueling a vehicle.

Synthetic enzymes

The researchers have now come up with a bioconversion process that overcomes these barriers (diagram, click to enlarge). Using synthetic biology approaches, Zhang and colleagues Barbara R. Evans and Jonathan R. Mielenz of ORNL, and Robert C. Hopkins and Michael W.W. Adams of the University of Georgia, are using a combination of 13 enzymes never found together in nature to completely convert polysaccharides (C6H10O5) and water into hydrogen when and where that form of energy is needed. This “synthetic enzymatic pathway” research appears in the May 23 issue of the open access journal Public Library of Science ONE.

Polysaccharides like starch and cellulose are used by plants for energy storage and building blocks and are very stable until exposed to enzymes. Just add enzymes to a mixture of starch and water and “the enzymes use the energy in the starch to break up water into only carbon dioxide and hydrogen,” says Y.H. Percival Zhang, assistant professor of biological systems engineering at Virginia Tech.

Starch in our tanks
A membrane bleeds off the carbon dioxide and the hydrogen is used by the fuel cell to create electricity. Water, a product of that fuel cell process, will be recycled for the starch-water reactor. Laboratory tests confirm that it all takes place at low temperature - about 86 degrees F - and atmospheric pressure.

The vision is for the ingredients to be mixed in the fuel tank of your car, for instance. A car with an approximately 12-gallon tank could hold 27 kilograms (kg) of starch, which is the equivalent of 4 kg of hydrogen. The range would be more than 300 miles, Zhang estimates. One kg of starch will produce the same energy output as 1.12 kg (0.38 gallons) of gasoline.

Since hydrogen is gaseous, hydrogen storage is the largest obstacle to large-scale use of hydrogen fuel. The American Department of Energy’s long-term goal for hydrogen storage was 12 mass percent, or 0.12 kg of hydrogen per one kg of container or storage material, but such technology is not available, said Zhang. Using polysaccharides as the hydrogen storage carrier, the research team achieved hydrogen storage capacity as high as 14.8 mass percent, they report in the PLOS article:
:: :: :: :: :: :: :: :: :: :: :: ::

The idea began as a theory. The research was based on Zhang’s previous work pertaining to cellulosic ethanol production and the ORNL and University of Georgia researchers’ work with enzymatic hydrogen production. UGA Distinguished Professor Adams is co-author of the first enzymatic hydrogen paper in Nature Biotechnology in 1996. The researchers were certain they could put the processes together in one pot. They tested the theory using Oak Ridge’s hydrogen detectors and documented that hydrogen is produced as they predicted.

Mielenz, who heads the Bioconversion Group in ORNL's Biosciences Division, attributed the successful research to a unique collaborative working relationship between scientists, lab divisions, and universities.

"Pairing our biomass conversion capabilities with facilities for studying renewable hydrogen production in the lab's Chemical Sciences Division was a key to this project," Mielenz said. "This also shows the value of partnerships with universities such as Virginia Tech and the University of Georgia."

It is a new process that aims to release hydrogen from water and carbohydrate by using multiple enzymes as a catalyst, Zhang said. “In nature, most hydrogen is produced from anaerobic fermentation. But hydrogen, along with acetic acid, is a co-product and the hydrogen yield is pretty low--only four molecules per molecule of glucose. In our process, hydrogen is the main product and hydrogen yields are three-times higher, and the likely production costs are low--about $1 per pound of hydrogen.

Over the years, many substances have been proposed as “hydrogen carriers,” such as methanol, ethanol, hydrocarbons, or ammonia - all of which require special storage and distribution. Also, the thermochemical reforming systems require high temperatures and are complicated and bulky. Starch, on the other hand, can be distributed by grocery stores, Zhang points out.

“So it is environmentally friendly, energy efficient, requires no special infrastructure, and is extremely safe. We have killed three birds with one stone,” he said. “We have hydrogen production with a mild reaction and low cost. We have hydrogen storage and transport in the form of starch or syrups. And no special infrastructure is needed.”

“The next R&D step will be to increase reaction rates and reduce enzyme costs,” Zhang said. “We envision that in the future we will drive vehicles powered by carbohydrate, or energy stored in solid carbohydrate form, with hydrogen production from carbohydrate and water, and electricity production via hydrogen-fuel cells.

“What is more important, the energy conversion efficiency from the sugar-hydrogen-fuel cell system is extremely high--greater than three times higher than a sugar-ethanol-internal combustion engine,” Zhang said. “It means that if about 30 percent of transportation fuel can be replaced by ethanol from biomass as the DOE proposed, the same amount of biomass will be sufficient to provide 100 percent of vehicle transportation fuel through this technology.”

In addition, the use of carbohydrates from biomass as transportation fuels will produce zero net carbon dioxide emissions and bring benefits to national energy security and the economy, Zhang said.

Interest to the South
The 'carbohydrate economy' is set to benefit those countries that can readily supply large quantities of industrial starch, sugar and cellulose. The developing world is a world leader in this respect and has a tremendous potential to grow.

If it ever becomes feasible to apply the technique developed by the researchers - just putting a starch and water solution in your tank - the main fuel will have to be processed starch. Theoretically it will be possible to extract the sugars from cellulose, but this would require additional processing steps.

Countries with the largest production potential for industrial starch can all be found in the tropics and the subtropics, where crops such as cassava, maize, sago and sweet potatoes grow that yield high quantities of the product (see our previous text, titled "Sweet potatoes and the carbohydrate economy").

Image: potato starch - soon powering our cars?

More information:
Zhang YP, Evans BR, Mielenz JR, Hopkins RC, Adams MW, High-Yield Hydrogen Production from Starch and Water by a Synthetic Enzymatic Pathway. PLoS ONE 2(5): e456, 2007, doi:10.1371/journal.pone.0000456


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