European Parliament ENVI Committee organises workshop on sustainability criteria for biofuels

Late last year, the European Parliament's Environment Committee adopted a first-reading report on the Commission's proposal to review the Fuel Quality Directive, which is aimed at lowering transportation fuels' environmental and health impact as well as to take into account new EU-wide targets on biofuels and greenhouse gas emissions reductions. On March 3, the European Council is likely to achieve a political agreement with regards to the revision. A week later, March 10, a first reading vote in the Parliament's plenary could see the adoption of the Directive if MEPs and member states succeed in agreeing on a common text.

European Parliament rapporteur MEP Dorette Corbey and shadow rapporteurs for the Fuel Quality Directive have decided that it is indeed worth the effort to enter into these first reading negotiations with the European Council. There is, however, one political issue that deserves full attention of the different committees, they feel: sustainability criteria for biofuels.

Recent scientific evidence suggests that the CO2 efficiency of some first generation biofuels is problematic, in particular if land use changes are taken into account (previous post). The vote in the Committee on Environment, Public Health and Food Safety (ENVI) approves sustainability criteria, including land use changes. Meanwhile the European Commission has presented its own proposal on renewable energies which contains sustainability criteria, although they are less stringent than the ones included in the ENVI-decision.

The European Parliament ENVI Committee, the TAUW Consulting and Engineering Company together with the EP's ENVI Committee Secretariat and the EP's Policy Department A will therefor be organising a workshop on "Sustainability criteria for biofuels".

The event is set to take place Tuesday 4 March 2008 in the European Parliament, Brussels. Participation in the workshop is free of charge and open to all, but requires registration beforehand. The programme looks as follows:
energy :: biofuels :: ethanol :: biodiesel :: social sustainability :: environmental sustainability :: greenhouse gas emissions :: land use change :: European Commission :: European Parliament ::

Part 1: The Institutional context
15:10 - Representative of the Slovenian Presidency
15:20 - Representative of the European Commission

Part 2: Panel of experts

General introduction - Technical aspects of sustainability criteria
15:30 - Greg Archer (LowCVP - Low Carbon Vehicle Partnership)

Criteria related to CO2 efficiency/saving and land use change
15:40 - Robert Edwards (Joint Research Centre, Italy, speaker to be confirmed)
15:50 - Bas Eickhout (MNP, Netherlands Environmental Assessment Agency)
16:00 - Debate: Questions and answers session

Criteria related to biodiversity and water
16:30 - Ms Berien Elbersen (Wageningen University and Research Center, Netherlands)
16:40 - Rothamsted Centre for Bio-energy and Climate Change, UK (to be confirmed)
16:50 - Debate: Questions and answers session

Criteria related to social issues
17:20 - Neil Judd (ProForest, UK)
17:30 - Debate: Questions and answers session

Part 3: Conclusions
18:00 - Closing remarks – Rapporteur MEP Ms Dorette CORBEY and Shadow Rapporteurs

Registration ends by Tuesday 26 February 2008. Interested parties that do not have a permanent entrance accreditation for the European Parliament should contact TAUW's organisers (address below) and provide them with your date of birth and nationality.

For further information and registration, please contact:
Jurgen Ooms
TAUW
P.O. Box 133
7400 AC Deventer
The Netherlands
Jurgen.Ooms [ at ] tauw.nl
Tel. +31 570 699 808
Fax +31 570 699 666

References:
EurActiv: The review of the EU's Fuel Quality Directive - Link Dossier.

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Malaysian-Japanese joint-venture to invest $308 million in 100,000ha plantation for biodiesel, biogas in Sarawak

Malaysia's state news agency Bernama reports that Carbon Capital Corporation Sdn Bhd will join hands with Japan Carbon Mercantile Co. Ltd to develop a multi-feedstock biodiesel plant in Tanjung Manis in Sarawak, as part of a major, US$100 billion energy and infrastructure development program for the state that aims to churn out 20GW of low carbon power by 2030. The plant will utilize jatropha curcas and palm oil for biodiesel and power production. The crops are to be established on 100,000 hectares of plantations. Besides biodiesel, a biogas plant will be build to utilize waste streams from the crop processing operations.

The project was announced at the launch of the "Sarawak Corridor of Renewable Energy" (SCORE) in Bintulu yesterday, which saw commitments for investments totalling RM 500 billion (€105.7/US$154.3bn). Prime Minister Datuk Seri Abdullah Ahmad Badawi said the proposed investments - amongst them commitments by mining giant Rio Tinto - were made in 24 memoranda of understanding (MOUs) signed during the launch.

SCORE is a large development project supposed to help reduce poverty and improve income distribution among the people in Sarawak by stimulating economic development in key sectors. It would add value to existing heavy industries, focus on development of natural resource-based industries (see overview below) and emphasise research and development capabilities the economic benefits of which should trickle down to local populations across the state.

The focus of SCORE is on the optimal utilisation of natural energy resources through the development of energy-intensive industries. Its goal is to establish power plants capable of generating 20 GW in as efficient a way as possible, preferrably by drawing on bioenergy, hydropower and natural gas. By concentrating energy-demanding activities in a single project, synergies are supposed to be developed that would lead to cleaner, more efficient and more sustainable production processes.

SCORE covers a geographic area of 70,000 square kilometers and will affect an estimated 600,000 people. The proposed investments announced at the opening of the project have exceeded the RM 334 billion (€70.6/US$103.1bn) that the Sarawak Government said was required to fully develop the corridor by 2030.

The Malaysian-Japanese biofuel joint-venture in Sarawak is part of SCORE's renewable energy focus. It covers five years and involves an initial investment of RM 1 billion (€212/US$308 million). The multi-feedstock biodiesel plant would have an annual capacity of about 240,000 tonnes per year and bulking facilities in Tanjung Manis while the jatropha curcas and oil palm plantations would cover an acreage of 100,000 hectares.

As for the biogas project, it would be undertaken under the Clean Development Mechanism (CDM) program in Sarawak, Carbon Capital. Both companies signed a Memorandum of Understanding (MoU) at the inauguration of SCORE:
energy :: sustainability :: biomass :: bioenergy :: biofuels ::biodiesel :: palm oil :: jatropha :: biogas :: natural resources :: deforestation :: Sarawak :: Malaysia ::

Carbon Capital, a Malaysian based company with offices in Bangkok, Kuala Lumpur, Kuching, New Delhi and Tokyo, provides end-to-end multi solutions in establishing CDM projects in Malaysia.

The CDM is an arrangement under the Kyoto Protocol allowing industrialised countries with a greenhouse gas reduction commitment to invest in projects that reduce omissions in developing countries as an alternative option to undertake expensive emission reductions in their own countries.

JCM, with its office in Nagoya, is a wholly owned member of Magna International Co. Ltd Japan, with its key businesses comprising trading in carbon credits and investment in CDM projects.


SCORE attracted both local and foreign investments in a range of sectors, including oil and gas, bioenergy as well as hydro resources, infrastructure, transport and communications - all sectors that require large investments to take scale advantages. Amongst the energy-intensive industries to be set up within the corridor are at least two aluminium smelters.

Sarawak Energy Bhd, Cahya Mata Sarawak Bhd (CMS) and Rio Tinto Aluminium Ltd inked a RM 5.25 billion deal for the supply of 1100MW of energy. Other deals signed included:

• Sarawak Energy and Press Metal Bhd for the supply of 510MW worth RM 2.5 billion
• Sarawak Energy and Sime Darby Bhd for 2,400MW from Bakun and undersea transmission line worth RM 22.5 billion
• Sarawak Energy and Tenaga Nasional Bhd to analyse energy options, develop coal potentials and infrastructure worth RM 50 billion
• Konsortium Galdasar Sdn Bhd and Yuh Yow Fisheries Taiwan for a 800ha aquaculture project worth RM 100 million
• Konsortium Galdasar and Shei Chui Oceanic Enterprise Taiwan for shipbuilding worth RM 40 million
• Bintulu Development Authority and Zinc Ox Resources England for zinc electro refinery plant worth US$350million
• Sarawak Energy and a consortium of banks for RM 3 billion to RM 20 billion in financial deals
• CMS and Rio Tinto on training for its aluminium smelter
• CMS and Rio Tinto and Aluminium Pechinery for the supply of technology to Salco aluminium smelter
• CMS, MMC Corp Bhd and Pan Kingdom Investment Co for financial deals worth US $1.5 billion

In terms of area of coverage and monetary investment, the Sarawak regional development corridor has topped the other development corridors in the country. SCORE stretches alongside Sarawak's coast, and has a total area of hinterland measuring 70,000 sq km is expected to be developed, affecting more than 600,000 people.

According to the development blueprint, the core projects would involve the setting up of power generation plants to churn out at least 20,000MW of electricity.

High priority sectors have also been identified for development – petroleum, aluminium, metal production, glass production, tourism, palm oil plantations, livestock, fishing, timber plantations, aquaculture and marine engineering which includes ship-building and ports construction.

Sarawak is Malaysia's province on Borneo Island, one of the world's most biodiverse regions, home to unique tropical forest ecosystems (map, click to enlarge). It is to be expected that SCORE will, despite its name, run into major environmental problems. Mining, metal processing, aquaculture, forestry, and palm oil production are all heavy industries with a problematic environmental footprint. Bioenergy plantations located in this region may lead to deforestation, even if they are based on a crop like jatropha which thrives well in poor, semi-arid zones.

Map: Major vegetation types of Borneo. Map modified from WWF's "Borneo: Treasure Island at Risk" report. The map is based on Langner A. and Siegert F.: Assessment of Rainforest Ecosystems in Borneo using MODIS satellite imagery. Remote Sensing Solutions GmbH & GeoBio Center of Ludwig-Maximilians-University Munich, in preparation, June 2005. Based on 57 single MODIS images dating from 11.2001 to 10.2002 with a spatial resolution of 250 m. Credit: Mongabay.

References:
Bernama: Malaysian-Japan JV In RM1 Bln Biodiesel, Jatropha & Biogas Deal In Sarawak - February 12, 2008.

Sarawak Corridor of Renewable Energy - website.

The Star: Sarawak corridor draws RM500bil - February 11, 2008.

The Star: SCORE set to make Sarawak a powerhouse of growth - February 12, 2008

TradingCharts: Sarawak Corridor of Renewable Energy to Help Reduce Poverty - February 11, 2008.

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A closer look at Direct Carbon Fuel Cells: the ultimate biomass conversion technology?

Last year, the director of the Department of Colloid Chemistry at the Max Planck Institute of Colloids and Interfaces, Prof Dr Markus Antonietti, developed an innovative technique with which any type of biomass can be converted into renewable and climate friendly 'designer coal'. Uses for the carbon are plenty, but professor Antonietti confessed that he and his researchers are part of a growing group of scientists who dream of a Direct Carbon Fuel Cell (DCFC) and a green carbon economy. As its name implies, a DCFC converts elemental carbon into electricity directly, and in a hyper-efficient way - the cells have almost twice the efficiency of most other types of fuel cells and double that of fossil fuel power plants.

What is more, the only byproduct of a DCFC's operation is very pure CO2 which can be contained in a concentrated stream and easily captured for downstream use or disposal. Because of the purity of the CO2 stream, capturing it would be far more cost-effective and efficient than capturing CO2 from conventional fossil fuel plants. Moreover, if the carbon feedstock for the fuel cell were to be derived from biomass, and the CO2 captured and sequestered, super-efficient carbon-negative electricity would be generated. That is: electricity the use of which results in the active removal of CO2 from the atmosphere (contrary to ordinary renewables like wind or solar, which merely prevent new emissions but don't go further than that). Quite a radical energy concept.

Now Prof Antonietti's dream is steadily becoming a reality, as a number of research institutions and companies are speeding up research and development into DCFCs. Let's have a closer look at these developments, which remain in their infancy.

A fuel cell is an electrochemical device that efficiently converts a fuel's chemical energy directly to electrical energy without burning the fuel. However, instead of using gaseous fuels, as is typically done, DCFCs use aggregates of extremely fine (10- to 1,000-nanometer-diameter) carbon particles distributed in a mixture of molten lithium, sodium, Yttria-stabilized zirconia or potassium carbonate at a temperature of 600 to 850°C. The overall cell reaction is carbon and oxygen (from ambient air) forming carbon dioxide and electricity (schematic, click to enlarge).

The reaction yields 80 percent of the carbon–oxygen combustion energy as electricity, yet no burning of the carbon takes place. DCFCs for stationary applications provide up to 1 kilowatt of power per square meter of cell surface area — a rate sufficiently high for practical applications. Some developers are designing DCFCs for mobile applications that can deliver energy densities in the range of 1,000–2,000 Wh/kg, far higher than any advanced battery.

Benefits
DCFC technology has several potential benefits over other fuel cells. First, it can use a wide variety of very abundant low cost carbonaceous fuels including coal, coke, tar, biomass and organic waste. Conventional fuel cells typically operate on gaseous fuels. The fuel (natural gas, propane, ethanol, etc.) is reformed to a hydrogen syngas, which is fed into the fuel cell stack. The DCFC, however, can operate directly on solid carbon fuel, which is stable, easy to store, handle and transport. DCFCs don't require the construction of an entirely new and expensive infrastructure - which is the case for hydrogen - nor do they lose the energy needed to turn fuel into gas.

Secondly, unlike hydrogen or methanol fuel cells, DCFC use no catalyst or costly noble metals like platinum. This cuts costs, and should increase reliability. The design of several fuel cell stack types is relatively simple, with costs expected to be $250/m2 of cell area depending on manufacturing components. Together with the balance of the system, researchers and companies put the total projected cost at a target of around $1000/kW. Given the abundance and low cost of the fuel, operating DCFCs would be by far the least costly of all fuel cell systems. In a carbon constrained world, with incentives to capture and store CO2, and with a carbon price, capturing and storing CO2 from DCFCs would be far less costly than doing the same at conventional fossil fuel plants.

Thirdly, DCFC are much more efficient than any other type of fuel cell and power plant. At high temperatures (more than 600 °C), the carbon fuel is electro-oxidized to CO2 at the anode compartment creating electricity. The benefit of converting solid carbon directly to electricity enables the efficiency to be around 80 percent - experimentally verified -, well above that of other fuel cells, and double that of conventional steam power plants. Routinely, a DCFC converts 80% of the heat that would have been liberated by combustion into electric power instead. This increased efficiency results in a beneficial payoff for DCFC development, as well as a reduction of CO2 emissions to about one-tenth of that of a modern coal firing power plant. When biomass is used as the feedstock, CO2 emissions are close to zero, and if the greenhouse gas is captured and stored, the energy becomes carbon-negative.

Table 1 outlines the operating characteristics of conventional fuel cells versus DCFCs (click to enlarge).

Biomass as an ideal feedstock
DCFC's can use a large number of carbon-rich fuels, but organic waste and biomass are at the center of the attention because they are renewable and clean, but also because they can be turned into the purest carbon fuel. The overall process of producing electricity in a DCFC from biomass gains efficiency by its simplicity. It involves only two steps: (1) drying (and/or pyrolysis, or hydrothermal carbonization) to obtain char, and (2) feeding the resulting fuel directly to the DCFC. Drying and/or pyrolysis or conversion into char via hydrothermal carbonization is required to create a carbon-rich particulate solid that can be fed to the DCFC fuel cell to produce power:
energy :: sustainability :: biomass :: bioenergy :: biofuels :: charcoal :: pyrolysis :: hydrothermal carbonisation :: carbon :: direct carbon fuel cell :: carbon capture :: carbon-negative :: efficiency :: climate change ::

The choice between drying or pyrolyzing the biomass before feeding it to the DCFC will depend on whether the energy contained in the waste gases resulting from the conversion of the dried biomass within the DCFC can be recovered efficiently, and whether the DCFC can be designed in a manner so that it is not fouled by the light gases and tars generated.

As a fuel, char produced from biomass and waste materials offers many benefits. It is inexpensive to produce and easy to store. Char is readily available to consumers worldwide from compacted beds with high-energy density particles. When combusted correctly, charcoal does not burden the atmosphere with CO2 emissions, and does not contribute to climate change. In contrast with fossil fuels, charcoal has no mercury, almost no sulfur, low nitrogen, and produces very little ash. It has high electrical conductivity, a large surface area, and many bonds that enable it to be very reactive at relatively modest temperatures.

DCFC developers favor fuels that are essentially pure carbon particles, with little inherent moisture, ash, sulfur, and nitrogen. Biomass from energy crops, waste paper products, structural wood, and a fraction of Municipal Solid Waste (MSW) can be converted into the type of fuel most highly valued by DCFC vendors by drying and pyrolysing.

DCFC Types
Several approaches to the development of DCFCs are underway. These can be grouped into three broad categories, depending on the type of electrolyte used.

DCFCs with a Molten Carbonate Electrolyte
Molten carbonate electrolytes are very good for DCFCs because they are highly conductive, have good stability when CO2 is present, and have an appropriate melting temperature for this application. The cell voltage is formed at the anode side and consumed at the cathode side, and there is an influence on the cell voltage by this partial pressure. Simulations have given results showing the system to be able to reach a net electrical efficiency of up to 78 percent.

DCFCs with a Molten Hydroxide Electrolyte
Molten hydroxides are very beneficial as electrolytes. They have a higher ionic conductivity and a higher activity of the carbon electrochemical oxidation. This results in a lower overpotential and a higher carbon oxidation rate, as well as a much lower operation temperature of about 600 °C. This decreases the cost as it allows the use of less expensive materials.

During carbon electro-oxidation in this type of fuel cell, there is the formation of carbonates. They undergo both a chemical process and an electro-chemical process. This fuel cell uses a pure graphite cylindrical rod, which acts as the anode and the fuel. It is immersed into molten sodium hydroxide and is served at the same time as the cathode. The cell is fed humidified air through a gas distributor in the bottom of the container.

To optimize the performance of the cell, one must look at the cathode material, air flow rate, operating temperature, and fuel cell scale. They system can be further optimized by changing the cell design, the electrode material, and the operating conditions.

DCFCs with YSZ-based Solid Electrolyte
The Yttria-Stabilized Zirconia (YSZ) design combines advances in the solid oxide and molten carbonate fuel cell technologies. Their components include a U-tube consisting of a metal mesh cathode current collector, a cathode layer, an electrolyte later, and a metal mesh anode current collector. This structure is immersed into a liquid anode made of a mixture of molten elements and carbon particles. When this mixture is stirred causing a flow mode, the fuel cell operates better since there is an increase contact between the carbon particles and the anode current collector, which enhances mass transport.

Current research
Around seven teams in the U.S. are actively investing in DCFC research and development. European and Japanese researchers are doing so as well, but information is limited.

Amongst the U.S. teams can be found researchers from Akron University, CellTech Power, Contained Energy, Direct Carbon Technologies, Scientific Applications & Research Associates (SARA), SRI, and the University of Hawaii.

The following table summarises their approaches to DCFC development (click to enlarge).

The Lawrence Livermore National Laboratory (LLNL) has a development program for the DCFC and recently made a breakthrough. The technology was the result of a two-year study funded by the Laboratory Directed Research and Development Program, and led to a DCFC that pushes the efficiency of using fossil fuels for generating electricity far closer to theoretical limits than ever before. Rights to the patented LLNL process have been acquired by Contained Energy.

The following are schematic illustrations and explanations of different DCFC types currently under development.

Early laboratory configuration of Contained Energy's fuel cell, based on LLNL's design

Contained Energy has exclusively licensed the DCFC technology developed by John Cooper at Lawrence Livermore National Laboratory (LLNL). The cathode in this technology is essentially a molten carbonate cathode, while the anode is a slurry of disordered carbon fuel and a carbonate eutectic. Under a Cooperative Research and Development Agreement (CRADA), Contained Energy engaged LLNL to develop the initial prototypes of its generation design; a single cell of 15W–30W output, and a five-cell bipolar stack of 75W–150W output.

This design has an area-specific resistance (ASR) of 0.69 Ω/cm2, which corresponds to a maximum theoretical power density for the cell of 280 mW/cm2. However, with variances in individual cell performance in the stack, and with realistic losses from interconnects, Contained Energy is targeting a maximum gross power density of 140-200 mW/cm2. Such a cell has operated for a period of 7 days.

In early development work at LLNL, the cathode was identified as the rate limiting subsystem. Under the work during the CRADA, the cathode has been improved with new materials and a proprietary activation procedure. Having improved the cathode, the separator is now the limiting constraint in the system, apparently due to a change in the chemical composition of the fabric YSZ separator produced by the supplier. The supplier is working to correct the problem. Meanwhile Contained Energy is also developing alternative separators that should have the same or superior performance characteristics.

Contained Energy is transferring the results of this CRADA to their devel-opment facility in Cleveland, OH. Contained Energy is simultaneously developing a different design for mobile applications that can deliver energy density in the range of 1,000–2,000 Wh/kg.

Akron University's fuel cell

All of Akron University's work described to date has been carried out on button cells lo-cated in a tubular apparatus. Most of the effort has been to test various combinations of anode and cathode catalysts. Typical experiments consist of placing a small amount of either raw coal or devolatilized coal on the button cell and either heating it up or dropping coal directly into a pre-heated cell. Test temperatures are normally in the range of 750–850 °C.

Power densities in the range of 50–150 mW/cm2 have been obtained during the relatively short test duration of a few hours. Ash build-up on the surface of the button cell reduces power density, but removing the loose ash from the cell surface and allowing fresh carbon to reach the surface restores power density to previous levels.

Direct Carbon Technologies DCFC

The first experiments with a fluidized bed of solid carbon fuel (i.e., synthetic carbon, coal and almond shell) particles provided peak power out-puts of 1-2 mW/cm2 at 900 °C with a flowing CO2 or He atmosphere. These experiments were done with an initial charge of 30 grams of solid carbon fuel and ran for more than 20 hrs. In some cases, erosion has been observed with delamination of the platinum anode.

Benchmarking experiments done for comparison reasons with gaseous fuels (3% H2 and 100 percent CO) in the absence of solid fuel in the bed and using the same cells similarly gave peak power densities of 1-2 mW/cm2. In both solid and gaseous fuel cases, the fuel cell behavior was dominated by ohmic loses due mostly to the high resistance of the thick partially sta-bilized zirconia (PSZ) tubular electrolyte employed in these experiments.

In contrast, experiments at those same conditions in the tubular reactor, with the synthetic carbon placed on button cells (featuring thin yttria sta-bilized zirconia ([YSZ] electrolyte wafers with Ni/YSZ cermet anodes) provided by Ceramatec (Salt Lake City, UT) and agitated by a flowing CO2 stream produced a peak power density in excess of 140 mW/cm2, which deteriorated in time due to sulfur interaction with the Ni anode. Similar experiments using fluidized coal in flowing He gas with other button cells gave peak power densities in excess of 40 mW/cm2, which also decayed in time. Again, benchmarking tests on these same button cells using gaseous fuels only gave comparable power densities. These results pointed to the importance of the microstructure, stability, and catalycity of the anode and its impact on cell performance.

In all cases, gas analyses of the reaction products verified oxygen balance around the cell, and indicated that all oxygen, supplied electro-chemically through the solid electrolyte into the solid fuel bed, is ac-counted for in the form of CO and CO2 in the flue stream. These prelimi-nary results demonstrated for the first time that one can electrochemically convert solid carbonaceous fuels into electricity in a single step inside a fluidized bed reactor.

Celltech DCFC

CellTech Power is developing a technology that uses a liquid tin anode in a solid oxide fuel cell. This system oxidizes molten tin (Sn) to tin oxides (such as SnO2) in the anode layer by oxygen ions produced in the cathode. The ions transit a typical Yttria-stabilized Zirconia (YSZ) electro-lyte to reach the anode such that electrons are released. Electricity can be produced directly by oxidizing Sn like a battery.

The SnO2 can be reduced back to Sn by carbon-containing solids or any reducing gases consisting of carbon, hydrogen, oxygen, nitrogen, and sulfur that enters the anode. During the Sn regeneration, the device operates like a fuel cell. The Sn anode is not poisoned by sulfur. With a cell open circuit voltage (OCV) of 0.8V, the CO/CO2 ratio is 0.2 in the anode effluent gas. Maintaining cell voltage (OCV) above 0.8V keeps the dissolved SnO2 concentration in the molten Sn at a level where precipitation of the oxide does not occur. This means that the CO-containing gaseous effluent that leaves the cell must be oxi-dized to complete the conversion of CO to CO2.

Several years ago, with $15 million raised from venture capital and private sources, CellTech built two 1 kW Gen 2 units fueled by natural gas, which operated for more than 2000 hrs continuously. In those Gen 2 units, the natural gas was conditioned to a stream also containing CO and hydrogen and fed to the Sn anode. During 2005-2006, with Defense Advanced Re-search Projects Agency (DARPA) funding, CellTech developed Gen 3.0 cells and stacks allowing direct conversion of waste packaging materials and JP-8 into electricity. Before 2005, the key limitations of this system had been low power density (with levels of 40 mW/cm2 with hydrogen fuel and 20 mW/cm2 with carbon/JP-8 fuel) and difficulty in manufacturing. These power densities had been deemed too low for portable and mobile power generation. With support from DARPA/Army recently in place, CellTech is developing a Gen 3.1 (2007) cell architecture for direct JP-8 conversion with improved power density. They have modified the porous media to allow higher mass transfer rates of heavy fuel molecules flowing to the anode and are developing a high electrical conductance tubular cathode.

In 2006, CellTech demonstrated power densities of 160 mW/cm2 for hydrogen and 80 mW/cm2 for JP-8. The Gen 3.1 design is expected to provide approximately four times reduction in weight and volume over the previous Gen 3.0. Gen 3.1 is projected to become competitive for number of portable and mobile applications such as military field battery chargers. The mid-term power density target for direct JP-8 conversion is 200 mW/cm2 (2008-2010); at this level the direct JP-8 conversion liquid Sn system becomes a formidable competitor for kilowatt or sub-kilowatt applications.

CellTech Power has several concepts of how to generate power from coal with this system, but has not completed a detailed flowsheet analysis. One approach involves feeding coal to a molten Sn bath anode to reduce SnO2 to Sn, then transferring the molten Sn to the cell arrays for oxidation to SnO2 and power production. Another concept is to use a fluidized bed of coal to take advantage of volatiles in coal, in which carbon in the coal is reacted with hot recycled CO2 and water to produce a CO-rich gas, which is then fed to the cell array to produce power.

University of Hawaii's DCFC, designed for use with charcoal

Charcoal has been used as the feedstock for a low temperature aqueous carbonate fuel cell that has operated as high as 245 °C. At this temperature the cell offered an open circuit voltage of 0.57 V and a short circuit current of 43.6 mA/cm2. At 220 °C, the power density was 6.3 mW/cm2. One possible explanation for the relatively low open circuit voltages resulted from the formation of carbon oxides on the anode that were accompanied by the release of CO2.

Thermodynamically, oxygen reduction at the cathode is more favorable at temperatures below 200 °C, however, improved anode performance could result from a higher temperature that could combust the carbon oxides ac-cumulated on the bicarbon anode material. Therefore, performance could be markedly improved if a split cell could be developed in which the cathode could be operated at below 200 °C and the anode at above 240 °C.

SARA's DCFC

SARA has evolved a new concept that uses different salts in two chambers separated by a porous separator plate. The cathode chamber contains molten potassium (KOH) or sodium hy-droxide (NaOH). Better results have been obtained with KOH. Moist air is bubbled into this chamber where the oxygen picks up electrons, resulting in the formation of OH- ions, which then transport through the separator membrane to enter the anode chamber. A basket of solid fuel particles is suspended in molten metal carbonates in the anode chamber. The OH- ions react with the solid fuel to produce CO3-2 ions and electrons. The CO3-2 ions also react with the coal to produce CO2 and electrons.

SARA recently observed that the electrolyte was stable over the course of a 500-hr experiment. A stackable design concept has been developed. They stated that the major challenges are the separator material and design, corrosion, and operating temperature. Power density numbers for this system are difficult to compare to the other systems reviewed because those numbers are based on the area of the separator rather an anode or cathode area.


Finally, one company, SRI has developed a concept based on feeding coal (as well as other carbon sources such as tar, biomass and waste paper/plastic) as a carbon rich solid fuel to a flowing molten salt, such as alkali metal carbonates. That mixture forms an electrically conducting anode when the carbon concentration reaches a value between 30 and 40 percent. Air is fed to a conventional SOFC cathode (typically strontium-doped lanthanum manganite [LSM]) which provides the oxygen ions that migrate through a solid oxide electrolyte (typically YSZ) and react with the solid fuel to produce electricity and CO2. SRI currently is operating a batch system which has up to six cathode/electrolyte tubes inserted into a single molten salt bath. Three types of tubes are being used: simplified, sub-scale, and full-scale

For the experiments conducted to date, the solid fuel is mixed with salt powder and the dry mixture is then dropped into the apparatus, which is then heated to its operating temperature of 800-950 °C. Power densities of approximately 300 mW/cm2 have been achieved. Lifetimes in excess of 1200 hours have also been demonstrated. A design for a 40 kW power system has been completed.


Integrating biomass pyrolysis and electricity production
As outlined above, there are several techniques for the production of a solid, carbon-rich, particulate fuel from various carbon-rich biomass and organic waste resources. These processes themselves generate heat and gases that can be utilized for the production of power. The question now is whether to integrate this operation with the DCFC's operation into a continuously operating system or to disperse the fuel preparation and electricity production functions to separate locations.

In the integrated case, it is necessary to transport the fuel to a central location and then transmit and distribute electricity from that location to a variety of users. The integrated approach offers an opportunity for maximum energy efficiency as a result of integration between the fuel preparation and fuel consumption operations as well as the opportunity to use that waste energy (thermal and methane) in other buildings or processing plants that could be co-located with the integrated unit.

Figure 2 (click to enlarge) shows a system with the potential for the highest energy efficiency and best opportunity for energy integration with co-located facilities. In this concept, feed material is dried at about 149 °C to drive water off from the wet biomass/MSW feed material. The dried feed is then pyrolized at 371 °C to drive off methane and carbon dioxide and produce char which is fed to the DCFC. Hot, CO2-rich anode product gas is recycled from the DCFC to the fuel dryer and pyrolyzer to provide the heat energy needed for those operations.

Excess energy in the pyrolyzer waste gas and in the CO2 rich anode-off gas can be used for steam generation and perhaps used in co-located energy consuming facilities.


Overall process efficiency
In a recent overview of DCFC technologies, researchers at the ERDC-CERL Fuel Cell Program of the U.S. Army Corps of Engineers undertook a basic calculation of the overall efficiency of the process to go from raw carbon-rich, biomass to electricity. Since the work of all the teams involved in developing DCFC technology is at very early stages of development, it is not likely that a fully integrated stack and fuel cell power plant will achieve the maximum theoretical efficiency of 80 percent that occurs in a single cell.

The researchers therefor assumed that the efficiency of converting the chemical energy (Higher Heating Value or HHV basis) in the dry carbon in the fuel to AC electricity in the DCFC is 65 percent. (Typical pulverized coal power plants convert the chemical energy in coal (on the same HHV basis) to electricity at 30–35 percent efficiency.)

Wood received in a power plant is assumed to contain 45 percent moisture. The typical carbon composition of dry-wood is assumed to be 50 percent. The heat of combustion of carbon when CO2 is the only product is 14,087 Btu/pound. Therefore the amount of pure carbon required to produce 1 MWH of electricity is 372 lb. If dry wood contains 50 percent carbon, then 372 lb of carbon is contained in 744 lb of dry wood.

Assuming that wet wood contains 45 percent moisture, then the amount of wet wood required for 168.7kg (372 lb) of carbon or 337.5kg (744 lb) of dry wood is 613.7kg (1353 lb). It follows that the amount of water contained in the wet wood is 276.2kg (609 lb). Drying wood by evaporation requires approximately 1000 Btu of heat per pound of water evaporated. Removing 276.2kg (609 lb) of water from wet wood requires 642.5MJ (609,000 Btu) of energy.

Converting 168.7kg (372 lb) of carbon into 1 MWH of electricity in a DCFC liberates 1,939 MJ (1,838,000 Btu) of waste heat in the fuel cell. The amount of energy contained in 1 MWH of electricity is 3,599,851Kj, from which it follows that the waste heat available is 1,939,192.9 kJ/MWH.

To maintain the fuel cell at its constant operating temperature of approxi-mately 760 °C (1400 °F), this waste heat must be removed from the DCFC system both by heating up the reactants that are fed to it, and cooling and recycling the gas product from the cell.

The waste heat available of 1,939 MJ/MWH (1,838,000 Btu/MWH) is far more than the 642 MJ/MWH (609,000Btu/MWH) required for wet wood drying. It can therefore be used to supply the heat needed for evaporation of the water from the wet wood.

The pyrolysis step also liberates a significant amount of methane. A reasonable assumption is that 10 percent of the mass of dry wood fed to a pyrolysis reactor will be produced as methane. Therefore, 613.7kg (1353 lb) of wet wood containing 744 lb of dry wood will yield about 33.7kg (74.4 lb) of methane. This amount of methane contains about 2,110 MJ (2,000,000 Btu’s) of energy, which could be used for drying or pyrolysis, or which could be exported for external uses.

Capturing CO2: green extreme
Countries with extensive coal reserves will continue to use coal as their primary source of electricity for many years to come. Biomass will be co-fired or used in dedicated power plants more often, but coal is set to remain the most widely used fuel. However, today's coal-fired power plants convert coal into electricity with relatively low efficiency, often not higher than 30 to 35 percent. In addition, coal is a source of toxic emissions, greenhouse gases and heavy metal pollutants when used in traditional combustion power plants. For coal dependent countries to enter a more environmentally sustainable and economically feasible way, a clean, efficient and direct process to convert coal into electrical energy is needed. This is where the DCFC can play a major role.

The CO2 from conventional fossil fuel power plants can be captured via a range of processes - pre-combustion, oxyfuel or post-combustion capture - but separating the gas from other flue or process gases is complex, energy demanding and requires expensive membranes or adsorption technologies. Nonetheless, large funds are being poured into such carbon capture and storage (CCS) research projects.

DCFCs have the major advantage that the CO2 stream they generate is extremely pure, allowing the climate destructive gas to be captured with ease. Legislation allowing CCS and a carbon price would give DCFCs a competitive advantage because they significantly lower the CO2 capture cost. If carbon-dioxide-capturing costs are included, DCFC system costs are estimated to be up to 50 percent less than those of current fossil fuel plants.

What is more, the fact that DCFCs can operate on the carbon contained in biomass, allows for the development of the most radically green type of energy system imaginable: one that results in negative emissions.

This is possible because as biomass grows it sequesters atmospheric CO2. When this gas is captured at the DCFC and then stored in geological formations such as depleted oil and gas fields or saline aquifers, the biomass actively removed CO2 from the atmosphere. Instead of being merely carbon-neutral (as other types of renewable energy are), the energy thus obtained would be carbon-negative.

Biopact readers are aware of research which shows that when biomass is burned in integrated gasification combined cycle (IGCC) plants, with the CO2 captured and stored, that negative emissions as high as minus 1000 grams of CO2 per KWh can be obtained. Solar photovoltaic (+100grams), wind (+30grams), non-CCS biomass (+30grams) and nuclear (+10-20 grams) are all carbon positive (graph, click to enlarge). Biomass burned in an IGCC coupled to CCS goes way beyond that and removes historic CO2 from the atmosphere. It is thus by far the most radical tool in the climate fight.

However, IGCCs are only moderately efficient, because they rely on the combustion of fuels; a considerable amount of the energy generated would be needed to capture the CO2, thus lowering the overall systems efficiency of IGCCs + CCS. DCFCs in contrast are up to twice as efficient and would thus allow the capture of CO2 in a far more efficient manner still. There are no calculations showing the overall efficiency of capturing CO2 from biomass by using part of the electricity generated in a DCFC, but it can be safely assumed that the process would be far more efficient than the same operation performed in a IGCC.

In short, the confluence of different factors in operating direct carbon fuel cells - the purity of the CO2 stream and the efficiency of the electricity generating process - makes it possible to imagine what is possibly the cleanest and greenest form of electricity production imaginable: efficiently generated negative emissions energy. Efficient DCFCs could help clean up the atmosphere and help us prevent climate change in the most drastic way.


References:
A large number of older, but key articles can be found online at the National Technology Energy Library: Direct Carbon Fuel Cell Workshop.

University of Hawaii; Hawaii Natural Energy Institute - Renewable Resources Research Laboratory: Biocarbon Fuel Cells.

Ronald H. Wolk, Scott Lux, Stacy Gelber, and Franklin H. Holcomb, Direct Carbon Fuel Cells: Converting Waste to Electricity [*.pdf], U.S. Army Corps of Engineers: ERDC-CERL Fuel Cell Program, September 2007

Antal, Michael J, Performance of a First Generation Aqueous Alkaline Biocarbon Fuel Cell, Ind. Eng. Chem. Res., 46 (3), 734 -744, 2007. DOI: 10.1021/ie061202s S0888-5885(06)01202-4

Cao, D., Y. Sun, G. Wang, Direct Carbon Fuel Cell: Fundamentals and Recent Developments, Journal of Power Sources, vol 167, No. 2, pp 250-257, May 15, 2007.

Hackett, Gregory A., John W. Zondlo, Robert Svensson. “Evaluation of Carbon Materials for Use in a Direct Carbon Fuel Cell,” Journal of Power Sources, vol 168, No. 1, pp 111-118, May 25, 2007.

Heydorn, Barbara, and Steven Crouch-Baker, “Direct Carbon Conversion: Progressions of Power,” The Fuel Cell Review, 2006.

Lawrence Livermore National Laboratory: Direct Carbon Fuel Cells.

SRI International: SRI International Presents Novel Direct Carbon Fuel Cell Technology at Industry Event - November, 11, 2005

SARA: Direct Carbon Fuel Cell.

Biopact: Back to black: hydrothermal carbonisation of biomass to clean up CO2 emissions from the past - May 26, 2007

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Georgia Power to purchase 50MW of biomass electricity from Greenway Renewable Power

Georgia Power and Greenway Renewable Power LLC, an affiliate of bioenergy company Rollcast Energy Inc., announce they have penned a 15-year deal for electricity that will be generated from environmentally-friendly biomass. The 50MW of power will come from a waste wood fueled facility to be located near Franklin in Heard County. The material used to make electricity will come from timber harvesting residuals and collection of non-commercial tree species, tree-thinnings, lumber scraps and wood waste reclaimed from landfills.

The contract comes less than a month after Georgia Power's deal with Yellow Pine Energy Company, under which it will buy another 50MW of biomass power from a 100MW plant (previous post).

The Greenway facility is scheduled to go into operation in 2010 and will produce 50 megawatts of renewable energy. Under the contract, Georgia Power will purchase 100 percent of the plant's capacity. One megawatt is enough energy to supply a Wal-Mart store or approximately 250 Georgia residences.

Wood waste is both plentiful and readily available in Georgia so it's a logical renewable energy choice for us. It's important that we continue to look for ways to expand the diversity of our generation mix by providing our customers with a cleaner form of energy with lower emissions. - Jeff Burleson, director of Resource Policy and Planning

With the addition of this contract, Georgia Power's energy portfolio includes contracts with six qualified biomass and renewable facilities throughout the state that generate 130 megawatts, or enough renewable energy to power more than 32,000 homes. These contracts include electricity generated from wood waste, landfill biogas and hydro. Georgia Power also buys energy from eight other renewable sources when available:
energy :: sustainability :: biomass :: bioenergy :: biofuels :: wood waste :: forestry :: bio-electricity :: renewable :: climate change :: Georgia ::

Rollcast Energy develops, owns and operates clean renewable power plants that use wood or biomass for fuel. The company seeks to provide customers with low-cost, environmentally benign electricity that reduces the nation's dependence on imported energy and provides sustainable jobs in local communities. This mission is accomplished through Rollcast's team of experts in independent power, its current pipeline of projects in development, and its relationship with customers.

The deal with Greenway Renewable Power comes after Georgia Power's recent contract Yellow Pine Energy Company, LLC, which operates a biomass-fired facility to be located near Fort Gaines, Ga. It signed a 20-year contract for electricity that will be generated from environmentally-friendly wood waste.

The Yellow Pine facility is scheduled to go into operation in 2010 and will produce 110 megawatts of renewable energy. Under the contract, Georgia Power will purchase almost half of the plant’s capacity, or about 50 megawatts.

Georgia Power is working to increase its renewable energy portfolio both through the purchase of energy from renewable generators and through investments in self-owned renewable generation. Additionally, Georgia Power will invest $43 million annually in 18 different demand response and energy efficiency programs, including six new programs recently approved by the Georgia Public Service Commission. These programs are expected to reduce electricity demand by 1,000 megawatts by 2010.

Georgia Power is the largest subsidiary of Southern Company, one of America's largest generators of electricity. The company is an investor-owned, tax-paying utility with rates well below the national average. Georgia Power serves 2.3 million customers in all but four of Georgia's 159 counties.

References:
Georgia Power: Georgia Power Seals Deal for Additional Power From a Renewable Generator - February 11, 2008.

Biopact: Georgia Power signs contract with biomass plant to buy output from 50MW - January 16, 2008

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GreenWood Resources in long-term agreement to supply poplar feedstock to ZeaChem's next-gen biorefinery

ZeaChem, Inc. and GreenWood Resources, Inc. (GWR), on behalf of GreenWood Tree Farm Fund, LP (GFTT) have announced the signing of a non-binding Letter of Intent to supply poplar tree (Pacific Albus) feed stock under a long-term agreement to support the operation of ZeaChem's cellulosic biorefinery. The biorefinery will initially produce 1.5 million gallons (5.7m liters) per year of next-generation biofuels based on ZeaChem's hybrid thermochemical and biochemical conversion process.

The biorefinery will be located near GTFF's Boardman, Oregon Forest Stewardship Council (FSC)-certified Pacific Albus tree farm in the Columbia River Basin. Additionally, ZeaChem and GWR agreed to explore increasing the scope of the relationship to accommodate additional capacity at this biorefinery and other future sites through the potential development of short-rotation poplar biomass energy tree farms integrated with ethanol conversion technology.

ZeaChem will be responsible for financing, constructing and operating the Bio-Refinery. The Bio-Refinery will be located at the Port of Morrow near GTFF's existing Pacific Albus tree farms. Initial engineering for the site has already begun.

We are pleased to have the opportunity to utilize a portion of the existing residual fiber from the GreenWood Tree Farms, and to bring our expertise in silviculture, germplasm, irrigation technology and global organizational reach together with ZeaChem's novel approach to producing cellulosic-based chemicals and ethanol. We look forward to working with ZeaChem as it commercializes its process and believe it sets the stage for the development of future short rotation poplar biomass energy tree farms integrated with emerging technologies for converting to ethanol. - Jeff Nuss, President and CEO of GWR

ZeaChem's approach to biorefining uses a combination of biochemical and thermochemical processing steps (previous post). The hybrid process improves yield by making more efficient use of biomass than conventional techniques do. It first breaks down cellulose into sugars, which are fermented by a highly efficient bacterium called Moorella thermoacetica (found in termite guts). Instead of producing ethanol, the microorganism generates acetic acid, a process that releases no carbon dioxide.

To convert acetic acid into ethanol it is first converted into ethyl acetate. This solvent is then reformed into ethanol with hydrogen. To get the hydrogen, ZeaChem lignin left over from the process that converts biomass into sugars. This material can be converted into a hydrogen-rich mixture of gases by gasification. The hydrogen is then combined with ethyl acetate to make ethanol, while providing power for the entire process. Zeachem's new hybrid processing technology has shown more than 40 percent better yield compared with conventional approaches, and it sees a theoretically possible improvement of 50 percent:
energy :: sustainability :: biomass :: bioenergy :: biofuels :: cellulosic ethanol :: lignocellulosic :: poplar :: energy crop :: fermentation :: gasification :: biotechnology ::

The Zeachem process allows the use of a wide range of lignocellulosic biomass feedstocks and allows both the fermentable and non-fermentable fractions to contribute chemical energy to the ethanol product.

Poplar trees have received much attention by the bioenergy community because they are fast growing and robust energy crops, that can be worked with in short rotation schemes (more here). The tree was the first to have its entire genome sequenced (earlier post).

Today's announcement is a win-win for both companies. It allows GreenWood to benefit from the development of the growing market demand for cellulosic-based chemicals and ethanol, while providing ZeaChem with a dedicated long-term cellulosic feed stock source from the leader in intensively-managed hybrid poplar trees for our planned initial 1.5 million GPY Bio-Refinery and other future sites. - James Imbler, President and Chief Executive Officer of ZeaChem, Inc.

GreenWood Resources(GWR) is a global leader in the development and management of short-rotation, high yield hardwood tree farms for a range of products and end uses.

The GreenWood Tree Farm Fund, LP, a $175,000,000 fund organized by GWR, has invested in the consolidation of existing high-yield, fast-growing tree farm assets in the Pacific Northwest. GTFF currently owns 35,000 acres of sustainable tree farms certified under FSC in the Columbia Basin in Oregon and Washington. Investment management for the GTFF is provided through GreenWood Capital Management North America, LLC (a majority control subsidiary of GWR).

GWR also provides tree farm property and irrigation management for GTFF. GTFF has also organized to capture unrealized value from its tree farms, by developing value-added processing with The Collins Companies of Portland, Oregon, to move logs into solid wood products markets. Collins provides management to the mills planned by GTFF, and marketing and sales activities for the FSC-certified Pacific Albus wood generated from the manufacturing. Please visit for more information.

ZeaChem Inc. builds and operates bio-refineries for the conversion of biomass into next-generation cellulosic ethanol fuel and cellulose-based intermediate chemicals. ZeaChem's hybrid bio-refining technology overcomes yield and emissions problems associated with the traditional biofuels business by using unique hybrid fermentation and chemical processes for the conversion of biomass to cellulosic-based chemicals and ethanol. ZeaChem's platform has the highest carbon and energy efficiency results of any known process, allowing the company to become the lowest cost producer of ethanol. Incorporated in 2002, ZeaChem is headquartered in Lakewood, CO with a laboratory and pilot plant in the San Francisco Bay Area.

References:
Biopact: ZeaChem uses termite gut microbe for ethanol: up to 50% yield increase -
February 07, 2008

Biopact: Virginia Tech researchers receive $1.2 million to study poplar tree as model biomass crop - June 26, 2007

Biopact: The first tree genome is published: Poplar holds promise as renewable bioenergy resource - September 14, 2006

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